Chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity.

Chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity† †Electronic supplementary information (ESI) available: All of the experimental details, crystallographic data collection and refinement statistics, the details of the chemical synthesis, and additional figures and tables. CCDC 1509668–1509670. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01041a Click here for additional data file. Click here for additional data file.

Single-crystalline molecular flasks: chemical transformation with bulky reagents in the pores of porous coordination networks.

Introduction In situ observation of solid-state reactions by X-rays provides direct information on reaction processes and final structures. Crystallographic analysis of reactions involving bulky reagents within crystals are also limited due to restricted diffusion in close-packed crystals and the often concurrent crystal degradation. Recently, we reported a robust coordination network complex p...

Effect of Water Gas Shift Reaction on the Non-Isothermal Reduction of Wustite Porous Pellet Using Syngas

Effect of water gas shift reaction (CO+H2O=CO2+H2) on wustite reduction has been investigated by a transient, non-isothermal mathematical model based on grain model. In this model, wustite porous pellet is reduced using Syngas, namely a mixture of hydrogen, carbon monoxide, carbon dioxide and water vapor. For this purpose, governing equations containing continuity equation of species and energy...

Porous ionic/molecular crystal composed of highly symmetric magnetic clusters.

A porous ionic/molecular crystal composed of discrete triakis tetrahedral Co(8) clusters with an ideal T(d) symmetry shows interesting magnetism and porosity.

Effect of Chemical Reaction on Bioconvective Flow in Oxytactic Microorganisms Suspended Porous Cavity

In this paper, the bioconvective flow in a porous square cavity containing oxytactic microorganism in the presence of chemical reaction is investigated. The bioconvection flow and heat transfer in porous media are formulated based on the Darcy model of Boussinesq approximation. The governing partial differential equations are solved using the Galerkin finite element method. The computational nu...